78978-83-3Relevant academic research and scientific papers
Acyl-isothiocyanates as efficient thiocyanate transfer reagents
Palsuledesai, Charuta C.,Murru, Siva,Sahoo, Santosh K.,Patel, Bhisma K.
supporting information; experimental part, p. 3382 - 3385 (2009/12/01)
An unprecedented transfer of a thiocyanate (-SCN) group from aroyl/acyl isothiocyanate to alkyl or benzylic bromide is observed in the presence of a tertiary amine. This process is most effective when the bromomethyl proton is less acidic, while the prese
Formation of 2-Imino-1,3-oxathioles and 2(3H)-Oxazolethione by the Rhodium(II) Acetate-Catalyzed Reaction of α-Diazocarbonyl Compounds with Isothiocyanates
Ibata, Toshikazu,Nakano, Hirofumi
, p. 3088 - 3093 (2007/10/02)
The rhodium(II) acetate-catalyzed reaction of various α-diazocarbonyl compounds with alkyl, phenyl, and benzoyl isothiocyanates gave 2-imino-1,3-oxathioles in good yields. 2(3H)-Oxazolethione was obtained as a byproduct only in the reaction of diazodimedo
Synthesis of N-acyl-1,3-oxathiol-2-imines
Kulka, Marshall
, p. 1557 - 1559 (2007/10/02)
A facile synthesis of N-acyl-1,3-oxathiol-2-imines, 7, is reported.It comprises the reaction of O-alkyl acylcarbamothioates, 4, with 2-chloroketones in the presence of alcoholic sodium alkoxide.The resulting O-alkyl-S-substituted-N-acylcarbonimidothiates, 6, undergo cyclization with elimination of alcohol, spontaneously, or upon heating in boiling toluene to form 7.
