78986-76-2Relevant academic research and scientific papers
Dipole-Stabilized Carbanions: Secondary (α-Lithioalkyl)alkylamine Synthetic Equivalents from N,N-dialkyl-2,2-diethylbutyramides
Reitz, David B.,Beak, Peter,Tse, Anthony
, p. 4316 - 4317 (1981)
Lithiation of N,N-dialkyl-2,2-diethylbutyramides adjacent to nitrogen followed by addition to an aldehyde or ketone, an acid-driven nitrogen to oxygen rearrangement, and basis hydrolysis provides secondary (α-lithioalkyl)alkylamine synthetic equivalents.
