79010-64-3Relevant academic research and scientific papers
DECARBONYLATION DES DITHIOCARBONATES: UNE VOIE D'ACCES GENERALE AUX COMPLEXES BINUCLEAIRES BIS-μ-(S-ALKYL)-HEXACARBONYLEDIFER
Lagadec, Armelle,Dabard, Rene,Misterkiewicz, Boguslaw,Le Rouzic, Arnette,Patin, Henri
, p. 381 - 388 (1987)
Dithiocarbonates R1SC(O)SR2 (IV) react with to afford the bis-μ-(S-alkyl)-hexacarbonyldiiron coordination compounds: I (R1=R2), II (R1R2=bridging hydrocarbon chain) and III (R1*R2) after a double fragmentation pattern accompanied by loss of carbonyl groups.This unexpected reactivity of ligands IV offers a general route to binuclear iron compounds such as I and II.Some reaction intermediates (V) which led to I, have been identified.However the redistribution of S-alkyl groupings which occurs during the complexation of IV (R1*R2) shows that the decarbonylation reaction can follow several pathways.
Dithioallophanic Acids : Interaction of Carbon Oxysulphide with S-Benzyl-N-phenyl/methylisothiocarbamide in Presence of Alkyl Halides
Dravid, R. N.,Chande, M. S.
, p. 498 - 500 (2007/10/02)
Interaction of carbon oxysulphide with S-benzyl-N-phenyl/methylisothiocarbamide in acetone/benzene in the presence of benzyl chloride affords benzyl thiocyanate, dibenzyl dithiocarbonate, S-benzyl-N-phenyl/methylthiocarbamate and S-benzyl-1-phenyl/methylamidino-3-phenyl/methylisothiocarbamide hydrochloride.The intermediate alkyl ester of the corresponding N-γ-substituted-β-S-benzyldithioallophanic acid could not be isolated.The mechanism for the formation of these products from the intermediate dithioallophanic acid has been rationalised.
