79036-47-8Relevant academic research and scientific papers
Synthetic applications of aminochlorocarbenes: A two-step conversion of N-methylformanilides into 3-arylamino-2-chloroindoles
Cheng, Ying,Zhan, Yu-Hua,Guan, Hai-Xia,Yang, Hua,Meth-Cohn, Otto
, p. 2426 - 2430 (2002)
The thermal cyclisation of 1,2-diarylamino-1,2-dichloroethenes (dimers of arylaminochlorocarbenes) in DMF affords 3-arylamino-2-chloroindoles in good yields (70-91%).
The surprising nucleophilic addition of aminochlorocarbenes to diethyl acetylenedicarboxylate and to oxalyl chloride: Quinolines and benzo[1,4]diazepines from N-alkylformanilides and oxalyl chloride in the presence of Huenig's base
Cheng, Ying,Yang, Hua,Meth-Cohn, Otto
, p. 3605 - 3610 (2007/10/03)
Vilsmeier reagents derived from N-methylformanilides undergo ready deprotonation with Huenig's base. In xylene, the derived nucleophilic arylaminochlorocarbenes bearing 4-methyl- and 4-methoxy-substituents react with acetylenedicarboxylates to give 2-(2-c
ZUR DEPROTONIERUNG VON CHLOROMETHYLENIMINIUMCHLORIDEN
Boehme, Horst,Sutoyo, Paulus
, p. 1671 - 1674 (2007/10/02)
Deprotonation of chloromethyleniminium chlorides (1, 13) leads to cis-trans-isomeres 1,2-diamino-1,2-dichloro-ethenes (3a, 3b resp. 14a; 14b); their reactivity is described.
