79061-41-9Relevant academic research and scientific papers
The ?-Bonded Palladium(II) Complexes of 2-Aryl-4,4-dimethyl-2-oxazolines
Izumi, Takeo,Watabe, Hiroyuki,Kasahara, Akira
, p. 1711 - 1714 (1981)
Reactions of 2-phenyl-4,4-dimethyl-2-oxazoline with lithium tetrachloropalladate(II) and palladium(II) acetate give dichlorobis(2-phenyl-4,4-dimethyl-2-oxazoline,3-N)palladium(II) and a cyclopalladated binuclear complex, di-μ-acetato-bisdipalladium(II), respectively.The latter complex is readily converted by a metathetical reaction with lithium chloride into its chloro-bridged analogue.The chloro-bridged complex reacts with triphenylphosphine to give the corresponding mononuclear ?-bonding palladium complex.All the complexes prepared in this study were characterized by means of IR and NMR spectroscopies.
