79061-79-3

Basic information

• Product Name: PPN[Mn(CO)2(NO)2]
• CAS NO: 79061-79-3
• Molecular Weight: 709.559
• Mol File: 79061-79-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: PPN[Mn(CO)2(NO)2](CAS DataBase Reference)
• NIST Chemistry Reference: PPN[Mn(CO)2(NO)2](79061-79-3)
• EPA Substance Registry System: PPN[Mn(CO)2(NO)2](79061-79-3)

Safety Data

• Hazardous Substances Data: 79061-79-3(Hazardous Substances Data)

Upstream product

• 37504-44-2 (acetonitrile)pentacarbonylmanganese(I) hexafluorophosphate 
• 10170-69-1 dimanganese decacarbonyl 
• 14100-30-2 pentacarbonylchloromanganese(I) 

Relevant articles and documents

New mixed carbonyl-nitro and -nitrito complexes of manganese and rhenium

Treatment of with Me3NO in CH2Cl2 in the presence of gave the anion cis-- which, on further reaction, yielded the new dianionic trimer 2- containing both bridging nitro- and nitrito-groups.Reactions of , cis--, - or 2- with also produce the same final product.The crystal and molecular structure of the + salt has been established by X-ray diffraction analysis.The molecule 2 crystallises in the triclinic space group P1-.Addition of to in CH2Cl2 yielded a series of mixed carbonyl-nitro/nitrito isomers, which have been characterised in solution.The unusual complex salt 3Cl has been characterised in the solid state by single-crystal X-ray diffraction methods.The molecule crystallises in the monoclinic space group P21/a.