79062-29-6Relevant academic research and scientific papers
New and simple one-step cobalt-catalyzed preparation of functionalized arylstannanes from the corresponding aryl bromides or iodides
Gosmini, Corinne,Perichon, Jacques
, p. 216 - 217 (2005)
The process for the preparation of functionalized arylstannanes from the corresponding aryl bromides or iodides was described. The corresponding arylstannane was detected by gas chromatography using an internal standard alkane. The two-step coupling react
Ni-Catalyzed Stannylation of Aryl Esters via C?O Bond Cleavage
Gu, Yiting,Martín, Rúben
supporting information, p. 3187 - 3190 (2017/03/17)
A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents via Csp2 ?O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C?heteroatom bond formations.
Generation and reaction of cyano-substituted aryllithium compounds using microreactors
Nagaki, Aiichiro,Kim, Heejin,Usutani, Hirotsugu,Matsuo, Chika,Yoshida, Jun-Ichi
, p. 1212 - 1217 (2010/06/13)
We developed a microflow method for the generation and reactions of aryllithiums bearing a cyano group, including o-lithiobenzonitrile, m-lithiobenzonitrile and p-lithiobenzonitrile. The method was effective at much higher temperatures than are required for conventional macrobatch reactions, by virtue of rapid mixing, short residence time, and efficient temperature control. In addition, reactions of o-lithiobenzonitrile with carbonyl compounds followed by trapping of the resulting lithium alkoxides with electrophiles were achieved in an integrated microflow system. The Royal Society of Chemistry.
