790662-58-7

Upstream product

• 790662-57-6 (2S,3R,5R,2'S,1''R)-1''-(3-(hydroxydimethylsilanyl)-5-{2-[3'-(4-methoxybenzyloxy)-2'-methylpropyl][1,3]dithian-2-ylmethyl}tetrahydrofuran-2-yl)prop-2''-yn-1''-ol 
• 790662-56-5 (2S,3R,5R,2'S,1''R)-1''-{(3-(dimethylphenylsilanyl)-5-{2-[3'-(4-methoxybenzyloxy)-2'-methylpropyl][1,3]dithian-2-ylmethyl}tetrahydrofuran-2-yl)}prop-2''-yn-1''-ol 
• 790662-67-8 (2S,3R,5R,1'R,2''S)-2-[1'-(tert-butyldimethylsilanyloxy)-3'-(triethylsilanyl)prop-2'-ynyl]-3-(dimethylphenylsilanyl)-5-{2-[3''-(4-methoxybenzyloxy)-2''-methylpropyl][1,3]dithian-2-ylmethyl}tetrahydrofuran 
• 790662-51-0 (2R,4R,5S,1'R)-5-[1'-(tert-butyldimethylsilanyloxy)-3'-(triethylsilanyl)prop-2'-ynyl]-4-(dimethylphenylsilanyl)tetrahydrofuran-2-carboxylic acid ethyl ester 
• 790662-66-7 (2R,4R,5S,1'R)-methanesulfonic acid [5-[1'-(tert-butyldimethylsilanyloxy)-3'-(triethylsilanyl)prop-2'-ynyl]-4-(dimethylphenylsilanyl)tetrahydrofuran-2-yl]methyl ester 
• 790662-52-1 (2R,4R,5S,1'R)-[5-[1'-(tert-butyldimethylsilanyloxy)-3'-(triethylsilanyl)prop-2'-ynyl]-4-(dimethylphenylsilanyl)tetrahydrofuran-2-yl]methanol 
• 790662-50-9 (1S,2R)-{[2-(tert-butyldimethylsilanyloxy)-4-(triethylsilanyl)-1-vinylbut-3-ynyl]dimethylsilanyl}benzene 
• 790662-65-6 (3R,4S)-4-(dimethylphenylsilanyl)-1-(triethylsilanyl)hex-5-en-1-yn-3-ol 
• 790662-54-3 (S)-2-[3-(4-methoxybenzyloxy)-2-methylpropyl][1,3]dithiane 

Downstream Products

• 790662-63-4 (1S,3S,4R,1'S,2''R,5''R,1'''R,E)-benzoic acid 1-[2'-(2-{5''-[1'''-(tert-butyldimethylsilyloxy)-3'''-iodoallyl]tetrahydrofuran-2''-ylmethyl}-[1,3]dithian-2-yl)-1'-methylethyl]-3-hydroxy-5-(4-methoxybenzyloxy)-4-methyl-3-(triisopropylsilyloxy)pentyl ester 
• 790662-70-3 (1S,3S,4R,1'S,2''R,5''R,1'''R)-benzoic acid 1-[2'-(2-{5''-[1'''-(tert-butyldimethylsilanyloxy)prop-2'''-ynyl]tetrahydrofuran-2''-ylmethyl}-[1,3]dithian-2-yl)-1'-methylethyl]-3-hydroxy-5-(4-methoxybenzyloxy)-4-methyl-3-(triisopropylsilyloxy)pentyl ester 
• 790662-61-2 (2R,5S,6S,2'R,5'R,1''R)-7-(2-{5'-[1''-(tert-butyldimethylsilanyloxy)prop-2''-ynyl]tetrahydrofuran-2'-ylmethyl}-[1,3]dithian-2-yl)-5-hydroxy-1-(4-methoxybenzyloxy)-2,6-dimethylheptan-3-one 
• 790662-68-9 (1R,2'R,5'R,2''S)-tert-butyl[1-(5'-{2-[3''-(4-methoxybenzyloxy)-2''-methylpropyl][1,3]dithian-2-ylmethyl}tetrahydrofuran-2'-yl)prop-2-ynyloxy]dimethylsilane 

Relevant academic research and scientific papers

Efficient protiodesilylation of unactivated C(sp3)-SiMe 2Ph bonds using tetrabutylammonium fluoride

(Chemical Equation Presented) The protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates.

Synthesis of the C11-C29 fragment of amphidinolide F

(Chemical Equation Presented) An efficient synthesis of the C(11)-C(29) fragment 31 of amphidinolide F has been accomplished via a diastereoselective [3 + 2]-annulation reaction of allylsilane 5 and ethyl glyoxylate to prepare the key tetrahydrofuran 15 a