790715-17-2Relevant academic research and scientific papers
Nucleophilic ortho allylation of aryl and heteroaryl sulfoxides
Eberhart, Andrew J.,Imbriglio, Jason E.,Procter, David J.
, p. 5882 - 5885 (2011/12/15)
Aryl and heteroaryl sulfoxides undergo ortho allylation upon treatment with Tf2O and allylsilanes. The method complements the use of sulfoxides to direct ortho-metalation and reaction with electrophiles as it allows allylic carbon nucleophiles to be added ortho to the directing group in a metal-free process. The versatile sulfide adducts can be selectively manipulated using various methods including Kumada-Corriu cross-coupling of the organosulfanyl group.
Highly regioselective nucleophilic carbon - Carbon bond formation on furans and thiophenes initiated by pummerer-type reaction
Akai, Shuji,Kawashita, Norihito,Satoh, Hideharu,Wada, Yasufumi,Kakiguchi, Keisuke,Kuriwaki, Ikumi,Kita, Yasuyuki
, p. 3793 - 3796 (2007/10/03)
(Chemical Equation Presented) The reactions of (phenylsulfinyl)furans or -thiophenes with carbon nucleophiles in the presence of trifluoroacetic anhydride allowed the nucleophilic installation of carbon functional groups on the furan and thiophene nuclei
