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16718-12-0

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16718-12-0 Usage

Synthesis Reference(s)

Tetrahedron Letters, 9, p. 5071, 1968 DOI: 10.1016/S0040-4039(00)72287-8

Check Digit Verification of cas no

The CAS Registry Mumber 16718-12-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,7,1 and 8 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 16718-12:
(7*1)+(6*6)+(5*7)+(4*1)+(3*8)+(2*1)+(1*2)=110
110 % 10 = 0
So 16718-12-0 is a valid CAS Registry Number.
InChI:InChI=1/C10H8S2/c1-2-5-9(6-3-1)12-10-7-4-8-11-10/h1-8H

16718-12-0 Well-known Company Product Price

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  • Alfa Aesar

  • (A13708)  2-(Phenylthio)thiophene, 97+%   

  • 16718-12-0

  • 1g

  • 315.0CNY

  • Detail
  • Alfa Aesar

  • (A13708)  2-(Phenylthio)thiophene, 97+%   

  • 16718-12-0

  • 5g

  • 1322.0CNY

  • Detail

16718-12-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-phenylsulfanylthiophene

1.2 Other means of identification

Product number -
Other names phenyl-(thien-2-yl)-sulphide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16718-12-0 SDS

16718-12-0Relevant articles and documents

A facile and convenient synthesis of 2-(arylthio)thiophenes, 2-(alkylthio)thiophene, and 2-(thiophenylthio)thiophene

Sang, Bok Lee,Jong-In, Hong

, p. 8439 - 8442 (1995)

2-(Arylthio)thiophenes, 2-(alkylthio)thiophene, and 2-(thiophenylthio)thiophene were prepared in high yield by simply mixing 2-iodothiophene and aryl, alkyl, or thienyl thiols at room temperature without solvent, base, and/or catalyst.

Rh(I)-Catalyzed Intramolecular Decarbonylation of Thioesters

Cao, Han,Liu, Xuejing,Bie, Fusheng,Shi, Yijun,Han, Ying,Yan, Peng,Szostak, Michal,Liu, Chengwei

, p. 10829 - 10837 (2021/07/28)

Decarbonylative synthesis of thioethers from thioesters proceeds in the presence of a catalytic amount of [Rh(cod)Cl]2 (2 mol %). The protocol represents the first Rh-catalyzed decarbonylative thioetherification of thioesters to yield valuable thioethers. Notable features include the absence of phosphine ligands, inorganic bases, and other additives and excellent group tolerance to aryl chlorides and bromides that are problematic using other metals to promote decarbonylation. Gram scale synthesis, late-stage pharmaceutical derivatization, and orthogonal site-selective cross-couplings by C-S/C-Br cleavage are reported.

Synthesis of thioethers, arenes and arylated benzoxazoles by transformation of the C(aryl)-C bond of aryl alcohols

Chen, Bingfeng,Han, Buxing,Liu, Mingyang,Meng, Qinglei,Song, Jinliang,Zhang, Pei,Zhang, Zhanrong

, p. 7634 - 7640 (2020/08/14)

Transformation of aryl alcohols into high-value functionalized aromatic compounds by selective cleavage and functionalization of the C(aryl)-C(OH) bond is of crucial importance, but very challenging by far. Herein, for the first time, we report a novel and versatile strategy for activation and functionalization of C(aryl)-C(OH) bonds by the cooperation of oxygenation and decarboxylative functionalization. A diverse range of aryl alcohol substrates were employed as arylation reagents via the cleavage of C(aryl)-C(OH) bonds and effectively converted into corresponding thioether, arene, and arylated benzoxazole products in excellent yields, in a Cu based catalytic system using O2 as the oxidant. This study offers a new way for aryl alcohol conversion and potentially offers a new opportunity to produce high-value functionalized aromatics from renewable feedstocks such as lignin which features abundant C(aryl)-C(OH) bonds in its linkages.

Surfactant-Type Catalyst for Aerobic Oxidative Coupling of Hydrazine with Thiol in Water

Ren, Xuanhe,Tang, Shanyu,Li, Longjia,Li, Jiao,Liang, Helong,Li, Ganzhong,Yang, Guanyu,Li, Heng,Yuan, Bingxin

, p. 8683 - 8690 (2019/07/08)

A series of PEG-functionalized nitrogen ligands were developed to conduct an aerobic oxidative cross-coupling reaction between alkyl- or aryl-hydrazines with thiols in water. This surfactant-type catalyst enables high efficiencies and selectivities, while tolerating a large variety of functional groups. The mother liquor is still catalytically active after five runs.

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