791070-36-5

Basic information

• Product Name: Imidodiphosphorous acid, phenyl-, tetrakis(2-methoxyphenyl) ester
• CAS NO: 791070-36-5
• Molecular Formula: C34H33NO8P2
• Molecular Weight: 645.585
• Mol File: 791070-36-5.mol

Chemical Properties

• CAS DataBase Reference: Imidodiphosphorous acid, phenyl-, tetrakis(2-methoxyphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Imidodiphosphorous acid, phenyl-, tetrakis(2-methoxyphenyl) ester(791070-36-5)
• EPA Substance Registry System: Imidodiphosphorous acid, phenyl-, tetrakis(2-methoxyphenyl) ester(791070-36-5)

Safety Data

• Hazardous Substances Data: 791070-36-5(Hazardous Substances Data)

Upstream product

• 39652-40-9 N,N'-bis(dichlorophosphino)aniline 
• 90-05-1 2-methoxy-phenol 

Downstream Products

• 791070-44-5 cis-[Mo(CO)4(PhN(P(OC6H4OMe-o)2)2-κP,κP)] 
• 947259-21-4 [Rh(μ2-Cl)(PhN(P(OC6H4OMe-o)2)2)]2 
• 947259-29-2 [Pd(I)Br(μ-PhN(P(OC6H4OMe-o)2)2)]2 
• 947259-27-0 NiBr₂(PhN(P(OC₆H₄OMe-o)2)2) 
• 947259-28-1 (η6-cymene)Ru(μ2-Cl)3Ru(Cl)(PhN(P(OC6H4OMe-o)2)2) 
• 947259-26-9 [RhCl(CO)(μ-PhN(P(OC6H4OMe-o)2)2)]2 
• 1013639-64-9 Ag2(trifluoromethanesulfonate)2[μ-PhN(P(OC6H4OMe-o)2)2]2 
• 1013639-53-6 AuCl[PhN(P(OC₆H₄OMe-o)2)2] 
• 1013639-52-5 (C₆H₅N(P(OC₆H₄OCH₃)2)2)Au₂Cl₂ 
• 1145951-92-3 [(AuCl)2(μ-phenylene-1,4-diaminotetra(phosphonite))] 
• 928300-34-9 [Cu2(μ2-I)(2,2'-bipyridine)2(PhN(P(OC6H4OMe-o)2)2)]I 
• 928300-33-8 Cu2(μ2-I)I(2,2'-bipyridine)(PhN(P(OC6H4OMe-o)2)2) 

Relevant articles and documents

Synthesis and derivatization, structures and transition metal (Mo(0), Fe(II), Pd(II) and Pt(II)) complexes of phenylaminobis(diphosphonite), PhN{P(OC6H4OMe-o)2}2

The synthesis, derivatization and coordination behavior of a new aminobis(diphosphonite), PhN{P(OC6Me-o)2} 2 (1) is described. The ligand 1 reacts with H2 O2, elemental sulfur or selenium to give the corresponding dichalcogenides PhN{P(E)(OC6Me-o)2}2 (E = O, 2; S, 3; Se, 4) in good yield. Reactions of 1 with Mo(CO) 6, Pd(NCCH3)2Cl2 and Pt(COD) Cl2 resulted in the formation of the chelate complexes, Mo(CO)4[PhN{P(OC6Me-o)2}2] (5) and MCl2[PhN{P(OC6Me-o)2} 2] (M = Pd,7; M = Pt, 8) whereas in the reaction of 1 with [CpFe(CO)2] 2 , one of the P-N bonds cleaves due to the metal assisted hydrolysis to give a mononuclear complex, [CpFe(CO){P(O) (OC6Me-o)2}{PhN(H)(P(OC6 Me-o) 2)}] (6). The molecular structures of 1, 4, 5 and 6 are determined by X-ray studies.