791130-77-3Relevant academic research and scientific papers
Visible-Light Organophotoredox-Catalyzed Synthesis of Precursors for Horner-Type Olefinations
Nebe, Marco M.,Loeper, Daniel,Fürmeyer, Fabian,Opatz, Till
supporting information, p. 2471 - 2476 (2018/04/30)
A metal-free photoredox-catalyzed α-heteroarylation of 2-bromophosphonoacetic esters allows the synthesis of precursors for Horner-olefinations from indoles in a single step. Numerous functional groups are tolerated in this photoinduced radical coupling u
Stereoselective preparation of (E)-α-bromoacrylates from mixtures of brominated ando phosphonates
Olpp, Thomas,Brueckner, Reinhard
, p. 2135 - 2152 (2007/10/03)
We prepared 69:31-11:89 mixtures of phosphonates 6b and 7b containing two phenoxy substituents, a CO2Et group, and 1 or 2 bromine atoms, respectively, at the interspersed methylene group. Deprotonating 64:36 mixtures of these reagents with NaH
