79158-69-3Relevant academic research and scientific papers
REGIO- AND STEREO-SELECTIVE ALKYLATION OF 3-TRIMETHYLSILYLMETHYL DIENOLATES. A NOVEL SYNTHESIS OF 3-ALKYLATED 2-METHALLYLSILANES.
Nishiyama, Hisao,Itagaki, Kazuyoshi,Takahashi, Kaoru,Itoh, Kenji
, p. 1691 - 1694 (2007/10/02)
Lithium and copper 3-trimethylsilylmethyl dienolate anions derived from easily available 3-trimethylsilylmethyl-3-butenoic acid and its methyl ester underwent regio- and stereo-selective alkylation. α-Alkylated products were readily transformed to 3-alkylated 2-methallylsilanes by pyrolysis.
