791635-41-1

Upstream product

• 791635-36-4 (3S,5R,7aR,11aS)-3-[[(tert-butyldiphenylsilyl)oxy]methyl]-5-hexyloctahydro-pyrrolo-1H-pyrrolo[2,1-j]quinolin-7(7aH)-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 138629-30-8 (S)-tert-butyl 2-((tert-butyldiphenylsilyloxy)methyl)-5-oxopyrrolidine-1-carboxylate 
• 791635-28-4 (2S,5S,6S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-((E)-3-formyloxy-non-1-enyl)-1-aza-spiro[4.5]decane-1-carboxylic acid tert-butyl ester 
• 791635-33-1 (2S,5S,6R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-((E)-1-hydroxy-non-2-enyl)-1-aza-spiro[4.5]decane-1-carboxylic acid tert-butyl ester 
• 791635-35-3 (2S,5S,6R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-((E)-non-2-enoyl)-1-aza-spiro[4.5]decane-1-carboxylic acid tert-butyl ester 
• 791635-31-9 2-(tert-butyl-diphenyl-silanyloxymethyl)-6-(3-heptanoyl-oxiranyl)-1-aza-spiro[4.5]decane-1-carboxylic acid tert-butyl ester 
• 791846-33-8 2-(tert-butyl-diphenyl-silanyloxymethyl)-6-[3-(1-hydroxy-heptyl)-oxiranyl]-1-aza-spiro[4.5]decane-1-carboxylic acid tert-butyl ester 

Downstream Products

• 791635-42-2 (3S,5R,7aS,11aS)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hexyl-decahydro-pyrrolo[2,1-j]quinoline 

Relevant academic research and scientific papers

Short synthesis of (+)-cylindricine C and formal total synthesis of (-)-lepadiformine

A short synthesis of (+)-cylindricine C (1c) and a formal total synthesis of (-)-lepadiformine (2) were achieved. The key strategy for the syntheses was a catalytic asymmetric Michael reaction using a two-center organocatalyst (11) (TaDiAS: Tartrate-deriv

Total syntheses of (+)-cylindricines C-E and (-)-lepadiformine through a common intermediate derived from an aza-Prins cyclization and Wharton's rearrangement

(Chemical Equation Presented) Enantioselective total syntheses of (+)-cylindricines C-E and (-)-lepadiformine through a common tricyclic intermediate are described here. These syntheses are concise and feature an aza-Prins cyclization and a seldom-used Wh