79175-51-2

Basic information

• Product Name: (Z)-2-dutereo-3-phenylacrylonitrile
• Synonyms: (Z)-2-dutereo-3-phenylacrylonitrile
• CAS NO: 79175-51-2
• Molecular Weight: 130.153
• Mol File: 79175-51-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-2-dutereo-3-phenylacrylonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-dutereo-3-phenylacrylonitrile(79175-51-2)
• EPA Substance Registry System: (Z)-2-dutereo-3-phenylacrylonitrile(79175-51-2)

Safety Data

• Hazardous Substances Data: 79175-51-2(Hazardous Substances Data)

Upstream product

• 1885-38-7 cinnamic nitrile 
• 2537-48-6 diethyl 1-cyanomethylphosphonate 
• 100-52-7 benzaldehyde 
• 37854-15-2 2-bromo-3-phenyl-2-propenenitrile 
• 24840-05-9 (Z)-cinnamonitrile 

Relevant articles and documents

Visible light-mediated metal-free double bond deuteration of substituted phenylalkenes

Various bromophenylalkenes were reductively photodebrominated by using 1,3-dimethyl-2-phenyl-1H-benzo-[d]imidazoline (DMBI) and 9,10-dicyanoanthracene. With deuterated DMBI analogs (the most effective was DMBI-d11), satisfactory to excellent isotopic yields were obtained. DMBI-d11 could also be regenerated from the reaction mixtures with a recovery rate of up to 50%. The combination of the photodebromination reaction with conventional methods for bromoalkene synthesis enables sequential monodeuteration of a double bond without the necessity of a metal catalyst. This journal is

THE WITTIG-HORNER REACTION IN HETEROGENEOUS MEDIA1-X: SYNTHESIS OF α DEUTERATED FUNCTIONAL OLEFINS USING POTASSIUM CARBONATE WITH DEUTERIUM OXIDE.

α-Labelled functional olefins ( percent D >95 percent) are prepared in high yields by the WITTIG-HORNER reaction in the presence of a 6M K2CO3- deuterium oxide solution at room temperature.