791817-03-3Relevant articles and documents
Regio- and Stereo-selective Oxidation of gem-Dimethyl Olefins via -Sigmatropic Rearrangement of Allyl Amine Oxides
Inoue, Seiichi,Iwase, Norimichi,Miyamoto, Osamu,Sato, Kikumasa
, p. 2035 - 2038 (2007/10/02)
Highly regio- and stereo-selective oxidation sequences are described for the efficient conversion of the gem-dimethyl olefin terminus of acyclic terpenes to terminal trans-allylic alcohols and trans α,β-unsaturated aldehydes.