79193-64-9Relevant academic research and scientific papers
Water control over the chemoselectivity of a Ti/Ni multimetallic system: Heck- or reductive-type cyclization reactions of alkyl iodides
Millan, Alba,Alvarez De Cienfuegos, Luis,Miguel, Delia,Campana, Araceli G.,Cuerva, Juan M.
supporting information, p. 5984 - 5987 (2013/02/23)
A versatile Ti/Ni multimetallic protocol is described for the efficient catalysis of two different reactions, namely a Heck- and reductive-type cyclization of alkyl iodides, in the absence or presence of water, respectively. Noteworthy, the versatility of
Reaction of allylsilanes and allylstannanes with alkynes catalyzed by electrophilic late transition metal chlorides
Fernandez-Rivas, Carolina,Mendez, Maria,Nieto-Oberhuber, Cristina,Echavarren, Antonio M.
, p. 5197 - 5201 (2007/10/03)
The intramolecular reaction of allylsilanes and allylstannanes with alkynes proceeds catalytically in the presence of Pt(II), Pd(II), Ru(II), and Au(III) chlorides. Although more limited, AgOTf also catalyzes the cyclization. Usually, PtCl2 as the catalyst in methanol or acetone gives the best results. The reaction proceeds by exo attack of the allyl nucleophile on the alkyne to form five- or six-membered ring carbocycles. The reaction generally proceeds with anti stereoselectivity. However, a terminally substituted trimethylsilyl derivative reacts by a syn-type addition. The intermediate alkenylpalladium complex has been trapped with allyl chloride to form an allylated derivative with an additional carbon-carbon bond.
