79240-16-7Relevant academic research and scientific papers
STANNANES IN SYNTHESIS: A NEW ROUTE TO 2-SUBSTITUTED-1,3-BUTADIENES VIA STEREOSELECTIVE ALLYLTIN FORMATION UNDER HOMOLYTIC CONDITIONS
Ueno, Yoshio,Sano, Hiroshi,Aoki, Seiichi,Okawara, Makoto
, p. 2675 - 2678 (2007/10/02)
α-(Hydroxymethyl)allyl tolylsulfones reacted with tributyltin hydride in the presence of azobisisobutyronitrile (AIBN) in refluxing benzene to give a allyltin derivatives which subsequently gave 2-substitued-1,3-butadienes upon distillation in good yield.
