72195-46-1Relevant academic research and scientific papers
Direct transformation of terminal alkynes to branched allylic sulfones
Xu, Kun,Khakyzadeh, Vahid,Bury, Timm,Breit, Bernhard
, p. 16124 - 16127 (2014)
A new strategy for the transformation of terminal alkynes to branched allylic sulfones was developed. Using a Rh(I)/DPEphos/benzoic acid catalyst system, terminal alkynes react with sulfonyl hydrazides to produce branched allylic sulfones with good to exc
REGIO- AND STEREOCONTROLLED SYNTHESIS OF ALLYLIC p-TOLYL SULFONES CATALYZED BY PALLADIUM (0) COMPLEX
Inomata, Katsuhiko,Yamamoto, Taku,Kotake, Hiroshi
, p. 1357 - 1360 (2007/10/02)
The reaction of allyl esters with sodium p-tolylsulfinate in tetrahydrofuran and methanol catalyzed by Pd(PPh3)4 gave the regio- and stereocontrolled allylic p-tolyl sulfones in good yields at room or lower temperature.
