79249-67-5Relevant articles and documents
Mechanism of Direct Side-chain Acylamination and Aminoarylation of 2- and 4-Picoline 1-Oxides
Abramovitch, Rudolph A.,Abramovitch, Dorota A.,Tomasik, Piotr
, p. 561 - 562 (2007/10/02)
The isolation of radical coupling products and the observation of appropriate C.I.N.D.P. signals suggest that most of the title reactions proceed by homolysis of the anhydro-bases (4) or (9) followed by radical recombinations; a diazo-oxy-Cope rearrangement may still account for the formation of α-acylamination products.