79256-98-7Relevant academic research and scientific papers
A CONVENIENT METHOD FOR THE SYNTHESIS OF HOMOALLYL ALCOHOL USING A NEW DESULFONYLATION METHOD
Kotake, Hiroshi,Yamamoto, Taku,Kinoshita, Hideki
, p. 1331 - 1334 (2007/10/02)
2-Tosyl homoallyl alcohol obtained by the reaction of allylic p-tolyl sulfone with aldehyde was found to be easily desulfonylated to homoallyl alcohol by the use of Pd(PPh3)4 as a catalyst and hydride ion as a nucleophile, without any side reactions.
STANNANES IN SYNTHESIS: A NEW ROUTE TO 2-SUBSTITUTED-1,3-BUTADIENES VIA STEREOSELECTIVE ALLYLTIN FORMATION UNDER HOMOLYTIC CONDITIONS
Ueno, Yoshio,Sano, Hiroshi,Aoki, Seiichi,Okawara, Makoto
, p. 2675 - 2678 (2007/10/02)
α-(Hydroxymethyl)allyl tolylsulfones reacted with tributyltin hydride in the presence of azobisisobutyronitrile (AIBN) in refluxing benzene to give a allyltin derivatives which subsequently gave 2-substitued-1,3-butadienes upon distillation in good yield.
