72195-49-4Relevant academic research and scientific papers
Direct transformation of terminal alkynes to branched allylic sulfones
Xu, Kun,Khakyzadeh, Vahid,Bury, Timm,Breit, Bernhard
supporting information, p. 16124 - 16127 (2015/01/09)
A new strategy for the transformation of terminal alkynes to branched allylic sulfones was developed. Using a Rh(I)/DPEphos/benzoic acid catalyst system, terminal alkynes react with sulfonyl hydrazides to produce branched allylic sulfones with good to exc
Preparation of some Allylic Sulphones; Base-catalysed Isomerisation and Deuteriation of Cyclohex-2-enyl p-Tolyl Sulphones
Knight, Derek J.,Lin, Peter,Russell, Simon T.,Whitham, Gordon H.
, p. 2701 - 2706 (2007/10/02)
A summary of the methods used in the preparation of a range of allylic sulphones is given.In the case of the conformationally biased sulphones (5) and (6) stereospecific preparation from the cis- and trans-5-t-butylcyclohex-2-en-1-ols was achieved by rear
Synthesis of (+/-)-Lavandulol and its Related Homoallylic Alcohol via Allyl Transfer from Sulphur to Tin
Ueno, Yoshio,Aoki, Seiichi,Okawara, Makoto
, p. 683 - 684 (2007/10/02)
(+/-)-Lavandulol and related homoallylic alcohols were prepared by the stannolysis of allylic sulphones and the subsequent hydroxymethylation of the resulting allylic stannanes with trioxan-BF3*OEt2.
