79265-34-2 Usage
General Description
2,5-Bistrimethylsilanylthiazole is a chemical compound with the molecular formula C9H18NSSi2. It is a heterocyclic compound that contains both sulfur and silicon atoms, and it is commonly used as a reagent in organic synthesis. The presence of the trimethylsilyl group on the thiazole ring makes this compound highly reactive, and it is often used as a precursor in the preparation of other organic compounds. It has been used in the pharmaceutical industry for the synthesis of various drugs, as well as in the development of new materials. Additionally, it has potential applications in the field of agrochemicals and in the production of specialty chemicals. Due to its unique properties and versatility, 2,5-Bistrimethylsilanylthiazole is a valuable chemical in the field of organic chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 79265-34-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,9,2,6 and 5 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 79265-34:
(7*7)+(6*9)+(5*2)+(4*6)+(3*5)+(2*3)+(1*4)=162
162 % 10 = 2
So 79265-34-2 is a valid CAS Registry Number.
InChI:InChI=1/C9H19NSSi2/c1-12(2,3)8-7-10-9(11-8)13(4,5)6/h7H,1-6H3
79265-34-2Relevant articles and documents
Efficient access to 5-substituted thiazoles by a novel metallotropic rearrangement
Zambon, Alfonso,Borsato, Giuseppe,Brussolo, Stefania,Frascella, Pietrogiulio,Lucchini, Vittorio
, p. 66 - 69 (2008/09/17)
A novel rearrangement process involving the migration of trimethylstannanyl or trimethylsilanyl groups around the thiazole ring provides access to either 2- or 5-metallated thiazoles by tuning the reaction conditions. The proposed mechanism, based on expe
Reactions of Trimethylsilylthiazoles with Ketens: A New Route to Regioselective Functionalisation of the Thiazole Ring
Medici, Alessandro,Pedrini, Paola,Dondoni, Alessandro
, p. 655 - 656 (2007/10/02)
2-Trimethylsilylthiazole (2) and 2,5-bis(trimethylsilyl)thiazole (6) undergo ipso-substitution of the 2-SiMe3 group with various ketens affording the thiazolyl-trimethylsiloxy-ethylenes (3) and (7), respectively, which are hydrolysed to the 2-acylthiazoles (4), whereas 5-trimethylsilylthiazole (8) undergoes attack at C-2 by dichloroketen giving the Michael-type adduct 2-dichloroacetyl-5-trimethylsilylthiazole (9c).
