79292-45-8Relevant academic research and scientific papers
METALLORGANISCHE LEWIS-SAEUREN XVIII. HYDRIDOIRIDIUM(III)-KOMPLEXE MIT DEN SCHWACH KOORDINIERTEN ANIONEN PF6- UND AlCl4- UND IHRE REAKTIONEN MIT WASSER; ROENTGENSTRUKTUREN VON +BF4- UND (PPh3)2(CO)(Cl)(H)IrOPOF2
Bauer, Herbert,Nagel, Ulrich,Beck, Wolfgang
, p. 219 - 230 (1985)
The preparation and properties of (Ph3P)2(CO)(Cl)(H)IrX (X = FPF5, ClAlCl3) are reported.The PF6 complex reacts with water to give the difluorophosphato compound (Ph3P)2(CO)(Cl)(H)IrOPOF2 which was characterized by X-ray structure analysis.The X-ray structure analysis of +BF4- shows hydrogen bridges between the coordinated water and the BF4- ion forming a dimer.
Hydrido- and Methyl-Iridium(III) Complexes with Labile Anionic Ligands; a Route to Cationic Iridium(III) Complexes
Olgemoeller, Bernhard,Bauer, Herbert,Loebermann, Hartmut,Nagel, Ulrich,Beck, Wolfgang
, p. 2271 - 2286 (2007/10/02)
Hydrido- and methyl-iridium(III) complexes (PPH3)2(CO)ClRIrX (1 - 4) (R = H, CH3) are formed by oxidative addition of acids HX with poorly coordinating anions X- (X- = O3SCF3-, O3SC4F9-, BF4-) and (CH3)3O+BF4-, respectively, to (PPh3)2(CO)ClIr.The excellent leaving groups X- can be substituted even by weak neutral ?- and ?-donors yielding cationic iridium(III) complexes +X- (5 - 9) (B = PPh3, CH3CN, H2O, (CH3)2CO, THF, C2H4).The structure of the key tetrafluoroborato complex (Ph3P)2(CO)Cl(H)IrFBF3 (3c) has been determined by X-ray structure analysis.
