METALLORGANISCHE LEWIS-SAEUREN XVIII. HYDRIDOIRIDIUM(III)-KOMPLEXE MIT DEN SCHWACH KOORDINIERTEN ANIONEN PF6- UND AlCl4- UND IHRE REAKTIONEN MIT WASSER; ROENTGENSTRUKTUREN VON +BF4- UND (PPh3)2(CO)(Cl)(H)IrOPOF2

Article abstract of DOI:10.1016/0022-328X(85)87434-9

The preparation and properties of (Ph3P)2(CO)(Cl)(H)IrX (X = FPF5, ClAlCl3) are reported.The PF6 complex reacts with water to give the difluorophosphato compound (Ph3P)2(CO)(Cl)(H)IrOPOF2 which was characterized by X-ray structure analysis.The X-ray structure analysis of <(Ph3P)2(CO)(Cl)(H)Ir(OH2)>⁺BF4^- shows hydrogen bridges between the coordinated water and the BF4^- ion forming a dimer.