Journal of Organometallic Chemistry p. 219 - 230 (1985)
Update date:2022-08-04
Topics:
Bauer, Herbert
Nagel, Ulrich
Beck, Wolfgang
The preparation and properties of (Ph3P)2(CO)(Cl)(H)IrX (X = FPF5, ClAlCl3) are reported.The PF6 complex reacts with water to give the difluorophosphato compound (Ph3P)2(CO)(Cl)(H)IrOPOF2 which was characterized by X-ray structure analysis.The X-ray structure analysis of <(Ph3P)2(CO)(Cl)(H)Ir(OH2)>+BF4- shows hydrogen bridges between the coordinated water and the BF4- ion forming a dimer.
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