79293-02-0Relevant articles and documents
Preparation and Some Reactions of Phenylmercury Thio- and Dithiocarboxylates
Kato, Shinzi,Hattori, Eiji,Sato, Hiroyuki,Mizuta, Masateru,Ishida, Masaru
, p. 783 - 790 (2007/10/02)
It has been found that the reaction of diphenylmercury with an equimolar amount of thio- or dithio acids gave the corresponding phenylmercury thio- (1) or dithiocarboxylates (2), quantitatively, which further react with thio- or dithio acids to give mercury bis(thio-) (3) or bis(dithiocarboxylates) (4).The phenylmercury dithio salts (2) were found to be the very useful thioacylating agents for primary and secondary amines.The reaction of mercury bis(thiocarboxylates) (3) with dithiocarboxylic acids gave the unsymmetrical thio- and dithiocarboxylic acid mercury salts (5) in good yield. - Keywords: Phenylmercury Thiocarboxylates