823-04-1

Basic information

• Product Name: PHENYLMERCURIC IODIDE
• Synonyms: PHENYLMERCURIC IODIDE;Iodo(phenyl)mercury;Mercury,iodophenyl-;Phenylmercury(II) iodide
• CAS NO: 823-04-1
• Molecular Formula: C₆H₅HgI
• Molecular Weight: 404.6
• Mol File: 823-04-1.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: PHENYLMERCURIC IODIDE(CAS DataBase Reference)
• NIST Chemistry Reference: PHENYLMERCURIC IODIDE(823-04-1)
• EPA Substance Registry System: PHENYLMERCURIC IODIDE(823-04-1)

Safety Data

• RIDADR: 2026
• HazardClass: 6.1(a)
• PackingGroup: II
• Hazardous Substances Data: 823-04-1(Hazardous Substances Data)

Upstream product

• 587-85-9 diphenylmercury(II) 
• 2097-19-0 1-phenyl-2,8,9-trioxa-5-aza-1-silabicyclo{3.3.3}undecane 
• 180210-25-7 (C₆H₅)Hg(N₃O₄) 
• 7681-11-0 potassium iodide 
• 368-47-8 phenyltrifluorosilane 
• 141-51-5 (Iodomethyl)mercuric iodide 
• 102973-85-3 (C₄N(SCF₃)4)HgC₆H₅ 
• 98-80-6 phenylboronic acid 
• 1010-20-4 phenyltin(IV) trimethoxide 
• 109462-64-8 phenyl(2,2',2''-nitrilotriphenoxy)stannane 
• 38795-88-9 phenylstannatrane 
• 4819-11-8 bis(iodomethyl)mercury 
• 960-16-7 tributylphenylstannane 
• 595-90-4 tetraphenyltin(IV) 

Downstream Products

• 31597-94-1 Hg(C₆H₅)(SC₆F₅) 
• 134-85-0 4-chlorobenzophenone 
• 92-52-4 biphenyl 
• 92-93-3 1-phenyl-4-nitrobenzene 

Relevant articles and documents

Dinitramide and its salts: 9. Mercury(II) dinitramidate, a new reagent in chemistry of organomercury compounds

The potentialities of synthesis on the basis of mercury(II) dinitramidate Hg(N3O4)2 in mercuration, addition to the double carbon-carbon bond, alkylation, and complexation are shown.

KINETICS AND MECHANISM OF MERCURIDESTANNYLATION OF PHENYLSTANNATRANES AND RELATED DERIVATIVES

The kinetics and mechanism of mercuridestannylation of phenylstannatrane derivatives, PhSn(OCH2CH2)3N and PhSn(OC6H4)3N have been investigated relative to model systems PhSnBu3, PhSn(OMe)3 in solvent MeOH.For the latter two, the reaction proceeded via the

Bis(Iodomethyl) Mercury as a CH2 Transfer Reagent

Bis(iodomethyl) mercury, Hg(CH2I)2, is an effective transfer agent of one CH2 group to olefins to form cyclopropanes.Transfer of the second group (i.e., from ICH2HgI) is not a favourable process.However, the ICH2HgI/Ph2Hg or the ICH2HgI/(PhCH2)2Hg couples serve to transfer the second CH2 group to olefins.