792948-34-6Relevant articles and documents
Synthetic study of (+)-anthramycin using ring-closing enyne metathesis and cross-metathesis
Kitamura, Tsuyoshi,Sato, Yoshihiro,Mori, Miwako
, p. 9649 - 9657 (2007/10/03)
Synthesis of (+)-anthramycin was examined. A pyrrolobenzodiazepine skeleton could be synthesized by reductive cyclization of pyrrolidine derivative, which was obtained by enyne metathesis. The conjugated enamide ester part of (+)-anthramycin derivative was constructed by cross-metathesis. Graphical Abstract.