79324-95-1

Basic information

• Product Name: [5-((E)-2-NITRO-VINYL)-FURAN-2-YL]-METHANOL
• Synonyms: [5-((E)-2-NITRO-VINYL)-FURAN-2-YL]-METHANOL;[5-(2-NITROVINYL)-2-FURYL]METHANOL
• CAS NO: 79324-95-1
• Molecular Formula: C7H7NO4
• Molecular Weight: 169.13
• Mol File: 79324-95-1.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 321.9°C at 760 mmHg
• Flash Point: 148.5°C
• Appearance: /
• Density: 1.371g/cm³
• Vapor Pressure: 0.00012mmHg at 25°C
• Refractive Index: 1.601
• PKA: 13.73±0.10(Predicted)
• CAS DataBase Reference: [5-((E)-2-NITRO-VINYL)-FURAN-2-YL]-METHANOL(CAS DataBase Reference)
• NIST Chemistry Reference: [5-((E)-2-NITRO-VINYL)-FURAN-2-YL]-METHANOL(79324-95-1)
• EPA Substance Registry System: [5-((E)-2-NITRO-VINYL)-FURAN-2-YL]-METHANOL(79324-95-1)

Safety Data

• Hazardous Substances Data: 79324-95-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H7NO4/c9-5-7-2-1-6(12-7)3-4-8(10)11/h1-4,9H,5H2/b4-3+

Upstream product

• 67-47-0 5-hydroxymethyl-2-furfuraldehyde 
• 75-52-5 nitromethane 
• 57-48-7 D-Fructose 

Relevant articles and documents

Facile synthesis of 5-hydroxymethylfurfural: A sustainable raw material for the synthesis of key intermediates toward 21,23-dioxaporphyrins

In a simple and conceptually designed method for the dehydration of fructose on a solid support, 5-hydroxymethylfurfural (HMF) was synthesized in more than 95% isolated yield from fructose under very mild conditions at room temperature. The loading of fructose on the solid support reduced the intermolecular interactions between fructose/intermediates, diminished the formation of polymeric material (humin) and increased the selectivity towards HMF formation. The synthesized HMF was readily converted into key intermediates toward the simpler synthesis of 21,23-dioxaporphyrins.