79356-79-9

Upstream product

• 108998-83-0 (S)-1,1,2-triphenyl-1,2-ethanediol 
• 5928-67-6 (S)-(+)-benzoin 
• 17199-29-0 (S)-Mandelic acid 
• 108-86-1 bromobenzene 
• 579-43-1 (1S,2R)-1,2-diphenylethane-1,2-diol 

Downstream Products

• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 79309-93-6 dimethyl 1-(2-hydroxy-1,2-diphenylethyl)phosphate 
• 103674-70-0 trans-2-(1,2,3,4-tetra-acetyl-6-β-D-glucosyl)-2-oxo-4,5-diphenyl-1,3,2-dioxaphospholan 

Relevant academic research and scientific papers

Synthesis of Chiral Phosphate Esters

A stereospecific route for the synthesis of chiral phosphate monoesters of known absolute configuration is described.

Analysis of the Chirality of 16O, 17O, 18O> Phosphate Esters by 31P Nuclear Magnetic Resonance Spectroscopy

A stereospecific method for cyclising D-glucose 6-16O, 17O, 18O>phosphate and adenosine 5'-16O, 17O, 18O>-phosphate to their conformationally locked six-membered cyclic phosphate diesters has been developed.Using 16O, 17O, 18O>phosphate esters of known absolute configuration it is shown by 31P n.m.r. spectroscopy, after esterification to the axial and equatorial triesters, that the cyclisation occurs with inversion of configuration.It is now possible, therefore, to determine the chirality at phosphorus of D-glucose 6-16O, 17O, 18O>phosphate and adenosine 5'-16O, 17O, 18O>phosphate by this procedure.