79357-22-5

Basic information

• Product Name: Ethyl 2-bromo-3-methyl-4-pentenoate
• Synonyms: Ethyl 2-bromo-3-methyl-4-pentenoate
• CAS NO: 79357-22-5
• Molecular Weight: 221.094
• Mol File: 79357-22-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ethyl 2-bromo-3-methyl-4-pentenoate(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl 2-bromo-3-methyl-4-pentenoate(79357-22-5)
• EPA Substance Registry System: Ethyl 2-bromo-3-methyl-4-pentenoate(79357-22-5)

Safety Data

• Hazardous Substances Data: 79357-22-5(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 4784-77-4 (E/Z)-crotyl bromide 
• 4784-77-4 (E)-1-Bromo-2-butene 

Downstream Products

• 486999-71-7 6-benzyl-5-(1-methyl-2-propenyl)-1H-pyrimidine-2,4-dione 
• 486999-69-3 ethyl 2-(1-methyl-2-propenyl)-3-oxo-4-phenylbutyrate 

Relevant articles and documents

Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO2et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reaction

What's in my pockets? By employing Suslick's bis-pocket porphyrin (ttppp), a reactive M=CHCO2Et complex and a trans-[M(CHR)(CO)] (M = Ru) complex have been structurally characterized by X-ray crystal analysis. The sterically encumbered ttppp ligand has a significant impact on both the diastereoselectivity and chemoselectivity in metalloporphyrin-catalyzed reactions of ethyl diazoacetate with conjugated aryl dienes.