79364-40-2Relevant academic research and scientific papers
Direct atom-efficient esterification between carboxylic acids and alcohols catalyzed by amphoteric, water-tolerant TiO(acac)2
Chen, Chien-Tien,Munot, Yogesh S.
, p. 8625 - 8627 (2005)
A diverse array of oxometallic species were examined as catalysts for a test direct condensation of benzoic acid and 2-phenylethanol in 1:1 stoichiometry. Besides group IVB MOCl2-XH2O and TiOX 2-xH2O, group VB VOCl2-xTHF and group IVB TiO(acac)2 were found to be the most efficient and water-tolerant catalysts for the test reaction. The new neutral catalytic protocol with the optimal TiO(acac)2 tolerates many stereo/electronic structural variations in both (di)-acid (1°-3° alkyl and aryl) and (di)alcohol (1°, 2° alkyl, and aryl) components with high chemoselectivity.
A CONVENIENT SYNTHESIS OF 2-DEOXY-D-RIBOSE
Harada, Taira,Mukaiyama, Teruaki
, p. 1109 - 1110 (2007/10/02)
Successive treatment of allyltin difluoroiodide, formed in situ by the oxidative addition of stannous fluoride to allyliodide, with 1,2-O-isopropylidene-D-glyceraldehyde and phenoxyacetyl chloride results in the predominant formation of erythro homoallyle
