793719-86-5Relevant academic research and scientific papers
Ruthenium-catalysed hydrogenation of alkynylstannanes with migration of the stannyl group
Shirakawa, Eiji,Morita, Ryotaro,Tsuchimoto, Teruhisa,Kawakami, Yusuke
, p. 13614 - 13615 (2007/10/03)
Molecular hydrogen adds to aliphatic and aromatic alkynylstannanes in the presence of a ruthenium catalyst, pushing the stannyl group to the adjacent carbon atom to give α-substituted vinylstannanes. This is the first achievement of hydrogenation of alkynylstannanes, which is applicable also to the deuteration affording precursors for an important class of deuterium-labeled compounds. Copyright
