79388-25-3Relevant academic research and scientific papers
Design and synthesis of a water-tolerant chiral indium complex: Application to one-pot three-component Mannich-type reactions in water
Xiao, Jian,Loh, Teck-Peng
, p. 815 - 817 (2007)
A novel chiral indium(III) camphorsulfonate complex prepared from indium trichloride, allyltributylstannane and (1S)-(+)-10-camphorsulfonic acid has been developed as a water-tolerant Lewis acid to afford high yields (up to 99%) in one-pot three-component
Three component synthesis of β-amino carbonyl compounds using indium trichloride-catalyzed one-pot Mannich-type reaction in water
Loh, Teck-Peng,Liung, Sarah B. K. W.,Tan, Kee-Leng,Wei, Lin-Li
, p. 3227 - 3237 (2007/10/03)
The use of indium trichloride as catalyst in a one-pot Mannich reaction in water gives high yields for the formation of β-aminoketones/esters/acids is described. The catalyst can be recycled when the reaction is complete (Loh T.-P.; Wei L.-L. Tetrahedron Lett. 1998, 39, 323). (C) 2000 Elsevier Science Ltd.
Water-accelerated aldol reaction of ketene silyl acetals with carbonyl compounds
Loh, Teck-Peng,Feng, Li-Chun,Wei, Lin-Li
, p. 7309 - 7312 (2007/10/03)
The aldol reactions of ketene silyl acetals with reactive aldehydes proceed smoothly in water to afford the corresponding aldol products in good yields. (C) 2000 Elsevier Science Ltd.
Novel one-pot Mannich-type reaction in water: Indium trichloride-catalyzed condensation of aldehydes, amines and silyl enol ethers for the synthesis of β-amino ketones and esters
Loh, Teck-Peng,Wei, Lin-Li
, p. 323 - 326 (2007/10/03)
Novel one-pot Mannich-type reaction between aldehydes, amines and silyl enol ethers is catalyzed by indium trichloride in water to give β-amino ketones and esters in moderate to good yields.
Efficient Activation of Acetals, Aldehydes, and Imines toward Silylated Nucleophiles by the Combined Use of Catalytic Amounts of 2 and TMS-CN under Almost Neutral Conditions
Soga, Tsunehiko,Takenoshita, Haruhiro,Yamada, Masaaki,Mukaiyama, Teruaki
, p. 3122 - 3131 (2007/10/02)
In the presence of catalytic amount of a transition metal compound such as 2, Co(acac)2, or NiCl2, trimethylsilyl cyanide smoothly reacts with acetals to form α-methoxy carbonitriles in good yields.In the coexistence of catalytic amounts of Rh
