79408-50-7Relevant academic research and scientific papers
Synthesis, characterization, and anticancer activity of dithiocarbamate ruthenium(II) complexes
Dou, Ye-Hong,Xu, Shou-De,Chen, Yi,Wu, Xiang-Hua
, p. 1219 - 1223 (2017/09/25)
Twelve arene and cyclopentadienyl ruthenium(II) dithiocarbamate complexes have been prepared and characterized by spectroscopicmethods. The structures of 3a and 3c have been determined by X-ray crystallography. Their in vitro antitumor activitieswere eval
Reactivity of the [CpM(PPh3)2]+ (M = Ru, Os) fragment with diethyldithiocarbamate
Lalrempuia,Suante, Hauzachin,Yennawar, Hemant P.,Kollipara, Mohan Rao
, p. 867 - 870 (2008/10/09)
This paper reports on the reaction of [CpM(PPh3)2(L)]+/0(Cp = η5-C5H5; M = Os, L = CH3CN, DMSO Br; M = Ru, X = Cl, CH3CN) with diethyldithiocarbamate (S2 CN
SUBSTITUTED CYCLOPENTADIENYLRUTHENIUM COMPLEXES CONTAINING (S,S) DONOR LIGANDS
Reventos, L. Ballester,Alonso, A. Gutierrez
, p. 179 - 186 (2007/10/02)
The complexes Ru(η-RC5H4)Cl(PPh3)2 (R = H, CH3, CH3CO) have been shown to react with the anionic S-S donor ligands M1S2CX, (M1 = Na, K, NH4+; X = OR', NR''2, CN) to give cyclopentadienyl dithiolate complexes of ruthenium(II).Analogous compounds have been obtained from thallium cyclopentadienide and Ru(S2CX)2(PPh3)2.Ru(η-CH3COC5H4)Cl(PPh3)2 (III) has been made by reaction between acetylcyclopentadiene, RuCl3(aq.), and PPh3 in absolute ethanol.Complexes of formula Ru(η-RC5H4)(S2CX)(PPh3)2, with the dithiolate ligand monodentate, are obtained when R = H, X = OC6H11; R = CH3, X = OCH3; R = H, CH3, X = CN.In the other cases studied the isolated complexes contain a bidentate S-S ligand.Steric effects as well as the electronic properties of dithiolate ligands, seem to influence the choice between the two coordination modes.Reaction of III with NaS2CNEt2 affords Ru(S2CNEt2)2(PPh3)2 as the sole product.Carbonylation of complex VI, Ru(η-C5H5)(S2COC6H11)(PPh3)2 takes place in solution, but the carbonyl complex could not be isolated.
CYCLOPENTADIENYL-RUTHENIUM COMPLEXES. 1 THE REACTIVITY OF SOME ?-CYCLOPENTADIENYL-BISTRIPHENYLPHOSPHINE-RUTHENIUM(II) COMPLEXES
Wilczewski, Tadeusz,Bochenska, Maria,Biernat, Jan F.
, p. 87 - 96 (2007/10/02)
Several ruthenium complexes of the CpRuX(PPh3)2 type, where X=Cl, Br, I, NCS, NCO, CN, BH4, H, D, and some of the CpRuS2CZ(PPh3) type, where Z=NR2 or OR, were obtained.The hydride CpRuH(PPh3)2 was obtained in high yield by reaction of CpRuCl(PPh3)2 with R
