79414-62-3Relevant academic research and scientific papers
La(OTf)3: An efficient promoter for thioglycoside activation in conjunction with N-iodosuccinimide
Mukherjee, Somnath,Mukhopadhyay, Balaram
experimental part, p. 2853 - 2856 (2011/02/22)
Use of La(OTf)3 as a Lewis acid promoter for N-iodosuccinimide-mediated activation of thioglycosides is reported. The glycosylation reactions proceeded smoothly with good to excellent yields and stereoselectivity. Georg Thieme Verlag Stuttgart
Glycosylation reactions with 'disarmed' thioglycoside donors promoted by N-iodosuccinimide and HClO4-silica
Mukhopadhyay, Balaram,Collet, Beatrice,Field, Robert A.
, p. 5923 - 5925 (2007/10/03)
Glycosylation of 'disarmed' thioglycosides promoted by NIS in the presence of HClO4 immobilized on silica compares very favourably with the accepted NIS-TfOH procedure.
From solution phase to "on-column" chemistry: Trichloroacetimidate-based glycosylation promoted by perchloric acid-silica
Mukhopadhyay, Balaram,Maurer, Sarah V.,Rudolph, Nadine,Van Well, Renate M.,Russell, David A.,Field, Robert A.
, p. 9059 - 9062 (2007/10/03)
Activation of ester-protected glycosyl trichloroacetimidate donors by perchloric acid immobilized on silica afforded 1,2-trans disaccharides in 60-90% yields. Applying this approach to one-pot sequential glycosylation resulted in efficient syntheses of th
