79415-42-2Relevant academic research and scientific papers
POLYBROMINATED AROMATIC COMPOUNDS VI. EXHAUSTIVE BROMINATION IN THE RING OF DEACTIVATED AROMATIC COMPOUNDS
Shishkin, V.N.,Bolusheva, I.Yu.,Lapin, K.K.,Tanaseichuk, B.S.
, p. 1303 - 1308 (2007/10/02)
A convenient method is developed for the synthesis of perbrominated aromatic compounds containing electronegative groups (NO2, CN, COOH) by exhaustive bromination of the starting compounds with bromine in concentrated sulfuric acid in oleum in the presence of mecuric oxide at 35-60 deg C.
POLYBROMO AROMATIC COMPOUNDS. I. SYNTHESIS OF SOME DERIVATIVES CONTAINING A PENTABROMOPHENYL RESIDUE
Tanaseichuk, B. S.,Rumyantseva, K. S.,Vasin, V. A.,Shishkin, V. N.,Rumyantsev, N. P.,et al.
, p. 1124 - 1128 (2007/10/02)
The synthesis of pentabromobenzyl bromide has been carried out, and its nucleophilic substitution reactions with alcohols, amines, sodium acetate, and silver nitrite have been studied.The C-Br bond in the bromomethyl group of pentabromobenzyl bromide readily undergoes homolysis, resulting in reductive dehalogenation.
