794527-14-3Relevant academic research and scientific papers
NITROGEN-CONTAINING MONODENTATE PHOSPHINES AND THEIR USE IN CATALYSIS
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Page 18-19; 25, (2008/06/13)
The present invention relates to novel nitrogen-containing monodentate phosphane ligands of formula (I) and to their use in catalytic reactions, especially in the improvement of haloaromatic compounds.
Dialkylphosphinoimidazoles as new ligands for palladium-catalyzed coupling reactions of aryl chlorides
Harkal, Surendra,Rataboul, Franck,Zapf, Alexander,Fuhrmann, Christa,Riermeier, Thomas,Monsees, Axel,Beller, Matthias
, p. 1742 - 1748 (2007/10/03)
N-Aryl-2-(dialkylphosphino)imidazoles and -benzimidazoles are conveniently prepared in one step from the corresponding heterocycles by selective deprotonation and quenching with chlorophosphines. The novel ligands are easily tunable and show good to excellent performance in palladium-catalyzed Suzuki reactions and Buchwald-Hartwig aminations of aryl and heteroaryl chlorides.
