79485-76-0Relevant academic research and scientific papers
CHEMISTRY OF METAL-DIENE COMPLEXES; A DIRECT, NEW PREPARATIVE ROUTE TO HYDRIDO-PLATINIUM(II) COMPLEXES
Clark, Howard C.,Goel, Anil B.,Goel, Sarla
, p. C25 - C28 (1981)
A new preparative route to hydrido-platinum(II) complexes, particularly those containing bulky phosphines which are inaccessible by other methods, involves the convenient reaction of phosphines with bis in methanol.A β-hydrogen elimination mechanism is described, as well as the preparation and use as hydrogenation catalysts of the complexes trans- where L=tertiary phosphine.
