Journal of Organometallic Chemistry p. C25 - C28 (1981)
Update date:2022-08-02
Topics:
Clark, Howard C.
Goel, Anil B.
Goel, Sarla
A new preparative route to hydrido-platinum(II) complexes, particularly those containing bulky phosphines which are inaccessible by other methods, involves the convenient reaction of phosphines with bis<(2-methoxy-5-cyclooctenyl)chloroplatinum> in methanol.A β-hydrogen elimination mechanism is described, as well as the preparation and use as hydrogenation catalysts of the complexes trans-<(2-CH3O-5-C8H12)Pt(L)Cl> where L=tertiary phosphine.
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(2005)Doi:10.1007/BF00846225
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(1982)Doi:10.1080/10426500500269497
(2006)Doi:10.1023/A:1013186600293
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(1982)
