79522-92-2

Upstream product

• 65556-30-1 1,6-di-O-acetyl-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 100-51-6 benzyl alcohol 
• 57783-76-3 benzyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 108-24-7 acetic anhydride 
• 73366-72-0 benzyl 4,6-O-benzylidene-α-D-mannopyranoside 
• 20888-02-2 1,6-anhydro-2,3,4-tri-O-benzyl-β-D-mannopyranose 
• 100-39-0 benzyl bromide 
• 182969-90-0 6,7,8-tris-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 89615-39-4 benzyl 2,3,4,6-tetra-O-benzyl-α-D-mannopyranoside 

Downstream Products

• 57783-76-3 benzyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 176040-72-5 benzyl O-(2,3,4-tri-O-acetyl-α-D-mannopyranosyl)-(1[*]6)-O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)-(1[*]6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 176040-69-0 benzyl O-(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)-(1[*]6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 176040-70-3 benzyl 6-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-mannopyranosyl)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 176200-10-5 benzyl 2,3,4-tri-O-benzyl-6-O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 176040-71-4 benzyl O-(2,3,4-tri-O-acetyl-6-O-chloroacetyl-α-D-mannopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)-(1<*>6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside 

Relevant academic research and scientific papers

Highly efficient chemoenzymatic synthesis of naturally occurring and non-natural α-2,6-linked sialosides: A P. damsela α-2,6- sialyltransferase with extremely flexible donor-substrate specificity

(Chemical Equation Presented) Just relax: A one-pot, three-enzyme chemoenzymatic synthetic approach is highly efficient for obtaining complex sialosides that contain diverse naturally occurring sialic acid modifications. α-2,6-Linked sialosides containing

Chemical synthesis of a hexasaccharide comprising the Lewis(x) determinant linked β-(1→6) to a linear trimannosyl core and the precursor pentasaccharide lacking fucose

Phenyl 2,3,4-tri-O-acetyl-6-O-chloroacetyl-1-thio-α,β-mannopyranoside (5) was condensed with benzyl O-(2,3,4-tri-O-benzyl-β-D-mannopyranosyl)-(1→6)-2,3,4-tri-O-benzyl-α -D-mannopyranoside (12) in the presence of NIS-triflic acid to give, after removal of the chloroacetyl group, the key intermediate, benzyl O-(2,3,4-tri-O-acetyl-α-D-mannopyranosyl)-(1→6)-O-(2,3,4-tri-O-benzy l-β-D-mannopyranosyl)-(1→6)-2,3,4-tri-O-benzyl-α-D-mannopyranoside (14). A similar condensation of 6 and 7 with acceptor 14, followed by the removal of protecting groups, afforded 16 and 18, respectively. These compounds are expected to be useful in specificity studies of an antibody raised against a related, synthetic antigen that we are recurrently investigating.

Bausteine von Oligosacchariden, XXX. Neue effektive β-Glycosidsynthese fuer Mannose-Glycoside. Synthesen von Mannose-haltigen Oligosacchariden

A new method was developed for the stereo selective synthesis of oligosaccharides containing a β-linked mannose-unit which were hitherto not available by direct synthesis.The glycoside synthesis is promoted by a silversilicate-catalyst which was precipita