79527-13-2

Basic information

• Product Name: DL-(1,3/2,4,6)-4-bromo-6-hydroxymethyl-1,2,3-cyclohexanetriol
• Synonyms: DL-(1,3/2,4,6)-4-bromo-6-hydroxymethyl-1,2,3-cyclohexanetriol
• CAS NO: 79527-13-2
• Molecular Weight: 241.082
• Mol File: 79527-13-2.mol

Chemical Properties

• CAS DataBase Reference: DL-(1,3/2,4,6)-4-bromo-6-hydroxymethyl-1,2,3-cyclohexanetriol(CAS DataBase Reference)
• NIST Chemistry Reference: DL-(1,3/2,4,6)-4-bromo-6-hydroxymethyl-1,2,3-cyclohexanetriol(79527-13-2)
• EPA Substance Registry System: DL-(1,3/2,4,6)-4-bromo-6-hydroxymethyl-1,2,3-cyclohexanetriol(79527-13-2)

Safety Data

• Hazardous Substances Data: 79527-13-2(Hazardous Substances Data)

Upstream product

• 70878-41-0 DL-1,2,3-tri-O-acetyl-(1,3/2,4,6)-6-acetoxymethyl-4-bromo-1,2,3-cyclohexanetriol 

Downstream Products

• 79527-17-6 DL-1,7:2,3-di-O-isopropylidene-(1,3,4/2,6)-6-hydroxymethyl-4-(p-toluenesulfonamido)-1,2,3-cyclohexanetriol 
• 79527-21-2 DL-N-<(3,4,6/5)-3,4,5,6-tetrahydroxy-1-cyclohexenylmethyl>-(1,2,4/3,5)-2,3,4-triacetoxy-5-(acetoxymethyl)cyclohexylamine 
• 79527-22-3 DL-N-<(3,4,6/5)-3,4,5,6-tetrahydroxy-1-cyclohexenylmethyl>-(1,2,4/3,5)-2,3,4-trihydroxy-5-(hydroxymethyl)cyclohexylamine 
• 79527-20-1 DL-N-<(3,4,6/5)-3,4,5,6-tetraacetoxy-1-cyclohexenylmethyl>-2,3:4,7-di-O-isopropylidene-(1,2,4/3,5)-2,3,4-trihydroxy-5-(hydroxymethyl)cyclohexylamine 
• 79527-21-2 Acetic acid (1S,2R,5S,6S)-2,5,6-triacetoxy-3-[((1R,2R,3R,4S,5S)-2,3,4-triacetoxy-5-acetoxymethyl-cyclohexylamino)-methyl]-cyclohex-3-enyl ester 
• 79527-24-5 Acetic acid (1R,2R,3S,4S,6R)-2,3-diacetoxy-4-acetoxymethyl-6-((1R,4R,5S,6S)-4,5,6-triacetoxy-3-acetoxymethyl-cyclohex-2-enylamino)-cyclohexyl ester 
• 38665-10-0 (1R,2R,3S,6S)-4-Hydroxymethyl-6-((1S,2S,3S,4R,5R)-2,3,4-trihydroxy-5-hydroxymethyl-cyclohexylamino)-cyclohex-4-ene-1,2,3-triol 
• 79527-22-3 (1S,2S,3S,4R)-5-[((1R,2R,3R,4S,5S)-2,3,4-Trihydroxy-5-hydroxymethyl-cyclohexylamino)-methyl]-cyclohex-5-ene-1,2,3,4-tetraol 
• 79527-20-1 Acetic acid (1R,4S,5S,6S)-4,5,6-triacetoxy-2-[((3aR,4R,5aS,9aS,9bR)-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-ylamino)-methyl]-cyclohex-2-enyl ester 
• 79527-23-4 Acetic acid (1S,2R,5R,6S)-5,6-diacetoxy-4-acetoxymethyl-2-((3aR,4R,5aS,9aS,9bR)-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-ylamino)-cyclohex-3-enyl ester 

Relevant articles and documents

Synthetic studies on the validamycins. IX. Synthesis of some racemic isomers of validoxylamine A

Two racemic isomers of validoxylamine A have been synthesized by use of coupling reactions of the protected DL-validamine and the allyl bromides, the precursors of the unsaturated branched-chain cyclitol moiety. The racemix diasteromers thus formed can be

SYNTHESIS OF SOME RACEMIC ISOMERS OF VALIDOXYLAMINE A

Two racemic isomers of validoxylamine A were synthesized by the condensation reaction of the blocked DL-validamine and the allyl bromide, the precursor of the unsaturated branched-chain cyclitol moiety.