79527-20-1

Upstream product

• 79527-19-8 DL-1,3,4-tri-O-acetyl-(1,2,4/3)-5-bromomethyl-5-cyclohexene-1,2,3,4-tetrol 
• 79527-15-4 DL-2,3:4,7-di-O-isopropylidene-(1,2,4/3,5)-2,3,4-trihydroxy-5-(hydroxymethyl)cyclohexylamine 
• 79527-14-3 D,L-1,7:2,3-di-O-isopropylidene-(1,3/2,4,6)-4-bromo-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 79527-13-2 DL-(1,3/2,4,6)-4-bromo-6-hydroxymethyl-1,2,3-cyclohexanetriol 
• 70878-41-0 DL-1,2,3-tri-O-acetyl-(1,3/2,4,6)-6-acetoxymethyl-4-bromo-1,2,3-cyclohexanetriol 
• 108-24-7 acetic anhydride 

Downstream Products

• 79527-22-3 DL-N-<(3,4,6/5)-3,4,5,6-tetrahydroxy-1-cyclohexenylmethyl>-(1,2,4/3,5)-2,3,4-trihydroxy-5-(hydroxymethyl)cyclohexylamine 
• 79527-22-3 (1S,2S,3S,4R)-5-[((1R,2R,3R,4S,5S)-2,3,4-Trihydroxy-5-hydroxymethyl-cyclohexylamino)-methyl]-cyclohex-5-ene-1,2,3,4-tetraol 
• 79527-21-2 Acetic acid (1S,2R,5S,6S)-2,5,6-triacetoxy-3-[((1R,2R,3R,4S,5S)-2,3,4-triacetoxy-5-acetoxymethyl-cyclohexylamino)-methyl]-cyclohex-3-enyl ester 
• 79527-21-2 DL-N-<(3,4,6/5)-3,4,5,6-tetrahydroxy-1-cyclohexenylmethyl>-(1,2,4/3,5)-2,3,4-triacetoxy-5-(acetoxymethyl)cyclohexylamine 

Relevant academic research and scientific papers

Synthetic studies on the validamycins. IX. Synthesis of some racemic isomers of validoxylamine A

Two racemic isomers of validoxylamine A have been synthesized by use of coupling reactions of the protected DL-validamine and the allyl bromides, the precursors of the unsaturated branched-chain cyclitol moiety. The racemix diasteromers thus formed can be

SYNTHESIS OF SOME RACEMIC ISOMERS OF VALIDOXYLAMINE A

Two racemic isomers of validoxylamine A were synthesized by the condensation reaction of the blocked DL-validamine and the allyl bromide, the precursor of the unsaturated branched-chain cyclitol moiety.