795305-75-8Relevant academic research and scientific papers
A systematic study of C-glucoside trisphosphates as myo-inositol trisphosphate receptor ligands. Synthesis of β-C-glucoside trisphosphates based on the conformational restriction strategy
Terauchi, Masaru,Abe, Hiroshi,Tovey, Stephen C.,Dedos, Skarlatos G.,Taylor, Colin W.,Paul, Michael,Trusselle, Melanie,Potter, Barry V. L.,Matsuda, Akira,Shuto, Satoshi
, p. 1900 - 1909 (2007/10/03)
β-C-Glucoside trisphosphates having a C2 side chain (3,7-anhydro-2-deoxy-D-glycero-D-gulo-octitol 1,5,6-trisphosphate, 11) and a C3 side chain (4,8-anhydro-2,3-dideoxy-D-glycero-D-gulo-nonanitol 1,6,7-trisphosphate, 12) were designed as structurally simpl
An efficient synthesis of β-C-glycosides based on the conformational restriction strategy: Lewis acid promoted silane reduction of the anomeric position with complete stereoselectivity
Terauchi, Masaru,Abe, Hiroshi,Matsuda, Akira,Shuto, Satoshi
, p. 3751 - 3754 (2007/10/03)
(Chemical Equation Presented) The reduction of glyconolactols having an anomeric carbon substituent by Et3SiH/TMSOTf proceeded with complete stereoselectivity to produce the corresponding β-C-glycosides when the substrates were conformationally restricted in the 4C 1-chair form by a 3,4-O-cyclic diketal or a 4,6-O-benzylidene protecting group. Thus, the efficient construction of β-C-glycosides was achieved on the basis of the conformation restriction strategy.
