795311-24-9

Upstream product

• 13329-40-3 4-Iodoacetophenone 
• 321155-39-9 dimethyl(2-pyridinyl)(vinyl)silane 

Downstream Products

• 795311-30-7 1-{4-[(E)-2-(Dimethyl-pyridin-2-yl-silanyl)-1-(4-methoxy-phenyl)-vinyl]-phenyl}-ethanone 
• 89510-56-5 1-{4-[(1E,3E)-4-(4-Acetyl-phenyl)-buta-1,3-dienyl]-phenyl}-ethanone 

Relevant academic research and scientific papers

Stereoselective synthesis of multisubstituted butadienes through directed Mizoroki-Heck reaction and homocoupling reaction of vinyl(2-pyridyl)silane

(Chemical Equation Presented) We have developed the homocoupling reaction of alkenyl(2-pyridyl)silanes mediated by Cul and CsF, in which the strong directing effect of the 2-pyridyl group was observed. The homocoupling reaction was successfully integrated with the Mizoroki-Heck reaction of vinyl(2-pyridyl)-silane with aryl halides, enabling a rapid and stereoselective synthesis of multisubstituted butadienes. From a relatively small compound library, it was possible to detect a number of fluorescent butadienes with a wide range of fluorescence color variations (blue to reddish-orange).