79547-03-8Relevant academic research and scientific papers
Synthesis of 3-fluoropyruvates from glycidic-α-cyanoesters
Chehidi,Chaabouni,Baklouti
, p. 237 - 241 (2007/10/03)
The decyanation of α-cyano-β-fluoro-α-hydroxyesters is achieved, at room temperature, by action of Ni(OAc)2. The corresponding 3-fluoropyruvates are obtained in good yields.
Ethyl 2-Benzyloxy-3,3-difluoropropenoate as a Novel Synthon of β-Fluoro-α-keto Acid Derivatives, Preparation and Reactions with Nucleophiles
Shi, Guo-qiang,Cao, Zhi-yao
, p. 1969 - 1970 (2007/10/02)
Ethyl 2-benzyloxy-3,3-difluoropropenoate 3, prepared from the readily obtainable ethyl trifluoropyruvate, reacts with a variety of nucleophiles to give β-fluoro-α-keto acid derivatives in high yield.
3-Substituted-3-fluoropyruvic acids and their esters and salts, and production thereof
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, (2008/06/13)
A 3-substituted-3-fluoropyruvic acid and its ester and salt of the formula: STR1 wherein R is a lower alkyl group, a lower alkanoyl group, a fluorinated lower alkanoyl group, a substituted or unsubstituted phenyl group or a substituted or unsubstituted py
Methode generale d'obtention des α-ceto esters β-fluores
Ourari, Ali,Condom, Roger,Guedj, Roger
, p. 2707 - 2710 (2007/10/02)
A general method of synthesis of 3-alkyl (or aryl) 3-fluoro 2-oxo esters is described.The opening of glycidic esters with HF-pyridine (70percent w/w) followed by oxidation with Jones reagent, give the corresponding derivatives of fluoropyruvic esters in good yields.
α Fluorination of Ketones. 1. Direct Fluorination of Pyruvic Acid Derivatives by Using Molecular Fluorine
Tsushima, Tadahiko,Kawada, Kenji,Tsuji, Teruji,Misaki, Susumu
, p. 1107 - 1110 (2007/10/02)
Direct fluorination of enol-type 3-substituted pyruvates, e.g., those having aromatic and acyl substituents, by using molecular fluorine proceeds smoothly to produce a mixture of keto- and enol-type 3-substituted 3-fluoropyruvates in moderate to good yiel
