79607-47-9

Upstream product

• 6752-49-4 (4aR,6S,8aR)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 
• 120401-20-9 methyl 4,6-O-benzylidene-2-deoxy-3-C-vinyl-α-D-ribo-hexopyranoside 
• 20880-50-6 [(4aR,6S,8aS)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-(8E)-ylidene]-acetic acid methyl ester 
• 79646-67-6 [(4aR,6S,8aS)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-(8E)-ylidene]-acetic acid methyl ester 

Downstream Products

• 120401-21-0 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-(formylmethylene)-α-D-erythro-hexopyranoside 
• 120401-22-1 Acetic acid 1-acetoxy-2-[(4aR,6S,8aS)-6-methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-(8E)-ylidene]-ethyl ester 
• 120401-23-2 [(Z)-2-((4aR,6S,8aS)-6-Methoxy-2-phenyl-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-yl)-vinyl]-dimethyl-amine 
• 79607-50-4 2,2,2-Trichloro-N-((4aR,6S,8S,8aS)-8-formyl-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl)-acetamide 
• 79607-49-1 2,2,2-Trichloro-N-((4aR,6S,8R,8aS)-6-methoxy-2-phenyl-8-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl)-acetamide 
• 79607-48-0 2,2,2-Trichloro-acetimidic acid 2-[(4aR,6S,8aS)-6-methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-(8E)-ylidene]-ethyl ester 

Relevant academic research and scientific papers

A Synthetic Approach to Actinobolin Analogs from D-Glucose

Synthesis of methyl 4,6-O-benzylidene-2,3-dideoxy-3-C--α-D-arabino-hexopyranoside (22), a common intermediate for the synthesis of actinobolin (1a), bactobolin (1b), ramulosin (2a) and 6-hydroxyramulosin (2b) from D-glucose

UNVERZWEIGTE UND R-C-N-VERZWEIGTE AMINOZUCKER DURCH TRICHLORACETIMIDAT-UMLAGERUNG

Trichloroacetimidates from carbohydrates with an endo- or an exocyclic allylic alcohol grouping rearrange under thermal conditions with formation of unbranched or R-C-N branched amino sugars.