79613-14-2Relevant academic research and scientific papers
Alternative Palladium-Catalyzed Vinylic C?H Difluoroalkylation of Ketene Dithioacetals Using Bromodifluoroacetate Derivatives
Tian, Shuangquan,Song, Xiaoning,Zhu, Dongsheng,Wang, Mang
, p. 1414 - 1419 (2018/04/10)
A palladium-catalyzed cross-coupling of α-oxo ketene dithioacetals and bromodifluoroacetate derivatives has been developed for the synthesis of a class of CF2-containing tetra-substituted olefins, which has potential to extend to drug design an
Reactions of Malonanilic Acid Ethyl Esters with Heterocumulenes
Rudorf, W.-D.,Koch, K.,Augustin, M.
, p. 637 - 646 (2007/10/02)
Malonanilic acid ethyl esters 1 react with carbon disulfide in the presence of sodium hydride to give disodium salts 2.Treatment of 2 with an alkylation reagent yields the openchain or cyclic ketene S,S-acetals 3 and 4, respectively.Adding only one equiva
