79617-37-1

Basic information

• Product Name: Ethanone, 1-(7-oxabicyclo[4.1.0]hept-3-yl)-
• CAS NO: 79617-37-1
• Molecular Formula: C8H12O2
• Molecular Weight: 140.182
• Mol File: 79617-37-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(7-oxabicyclo[4.1.0]hept-3-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(7-oxabicyclo[4.1.0]hept-3-yl)-(79617-37-1)
• EPA Substance Registry System: Ethanone, 1-(7-oxabicyclo[4.1.0]hept-3-yl)-(79617-37-1)

Safety Data

• Hazardous Substances Data: 79617-37-1(Hazardous Substances Data)

Upstream product

• 106-87-6 4-vinylcyclohexene dioxide 

Relevant articles and documents

Selective catalyzed-rearrangement of terminal epoxides to methyl ketones

Terminal epoxides of the type {A figure is presented} have been selectively converted into methyl ketones by various catalysts. Some lanthanide derivatives, MnI2, and Co2(CO)8 gave the best results. The rearrangement of internal epoxides into ketones is much slower, allowing specific transformation of terminal epoxides. The scope of the reaction and tentative mechanisms are discussed.