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Product FOB Price Min.Order Supply Ability Supplier
4-vinylcyclohexene dioxide
Cas No: 106-87-6
No Data 1 Kilogram Metric Ton/Day Wuhan Shengmao Corp Contact Supplier
4-Vinylcyclohexene dioxide
Cas No: 106-87-6
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality 4-Vinylcyclohexene Dioxide supplier in China
Cas No: 106-87-6
No Data No Data Metric Ton/Day Simagchem Corporation Contact Supplier
106-87-6 7-Oxabicyclo[4.1.0]heptane,3-(2-oxiranyl)-
Cas No: 106-87-6
USD $ 40.0-50.0 / Gram 1 Gram 1000 Metric Ton/Day WUHAN MULEI NEW MATERIAL CO., LTD Contact Supplier
1-Vinyl-3-cyclohexene dioxide
Cas No: 106-87-6
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
TIANFU-CHEM - 4-VINYLCYCLOHEXENE DIOXIDE
Cas No: 106-87-6
USD $ 1000.0-1000.0 / Kilogram 1 Kilogram 10 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier
Manufacturer supply CAS 106-87-6 with best quality
Cas No: 106-87-6
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
7-Oxabicyclo[4.1.0]heptane,3-(2-oxiranyl)- 106-87-6
Cas No: 106-87-6
No Data 1 Kilogram 10000 Metric Ton/Month Shanghai Upbio Tech Co.,Ltd Contact Supplier
Vinylcyclohexene dioxide manufacturer
Cas No: 106-87-6
No Data No Data No Data Shaanxi Mingqi Chemical Co., Ltd Contact Supplier
High Purity 4-Vinylcyclohexene dioxide Cas No: 106-87-6
Cas No: 106-87-6
USD $ 1.0-3.0 / Gram 10 Gram 1000 Kilogram/Month Wuhan Monad Medicine Tech Co.,LTD Contact Supplier

106-87-6 Usage

Uses

Vinylcyclohexene dioxide (VCD) is used to study toxicity as an ovotoxin,and it's also used to understand its mechanisms of toxicity towards ovarian follicles and effects on epithelial differentiation.

General Description

Clear colorless liquid. Sets to glass at -67°F. Faint olefinic odor.

Air & Water Reactions

Water soluble. Hydrolyzes slowly in water.

Reactivity Profile

4-VINYLCYCLOHEXENE DIOXIDE reacts with active hydrogen compounds (such as alcohols and amines). . Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Chemical Properties

colourless liquid. Combustible.

Definition

ChEBI: The diepoxide of 4-vinylcyclohexene.
InChI:InChI=1/C8H12O2/c1-2-6-7(10-6)3-5(1)8-4-9-8/h5-8H,1-4H2

106-87-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma (94956)  Vinylcyclohexenedioxide  purum, for electron microscopy, mixture of isomers, ≥96.0% (GC) 106-87-6 94956-250ML 8,558.55CNY Detail
Sigma (94956)  Vinylcyclohexenedioxide  purum, for electron microscopy, mixture of isomers, ≥96.0% (GC) 106-87-6 94956-100ML 4,278.69CNY Detail

106-87-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-vinylcyclohexene dioxide

1.2 Other means of identification

Product number -
Other names 4-vinylcyclohexene diepoxide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:106-87-6 SDS

106-87-6Synthetic route

4-ethenylcyclohexene
100-40-3

4-ethenylcyclohexene

4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

Conditions
ConditionsYield
With 2,2,2-Trifluoroacetophenone; dihydrogen peroxide In acetonitrile; tert-butyl alcohol at 20℃; for 1h; Green chemistry;88%
With fluorosulfonyl fluoride; dihydrogen peroxide; potassium carbonate In 1,4-dioxane; water at 20℃; for 1h;81%
With hypochloric acid Behandeln des Reaktionsproduktes mit wss. Natronlauge.;
4-ethenylcyclohexene
100-40-3

4-ethenylcyclohexene

A

4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

C8H12O

C8H12O

Conditions
ConditionsYield
With C20H26FeN4(2+)*2CF3O3S(1-); dihydrogen peroxide; acetic acid In acetonitrile at 0℃; for 0.166667h; regioselective reaction;A n/a
B 74%
1,1,3,3-tetrachloropropanone
632-21-3

1,1,3,3-tetrachloropropanone

4-ethenylcyclohexene
100-40-3

4-ethenylcyclohexene

A

4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

B

1,2-Epoxy-4-vinylcyclohexane
106-86-5

1,2-Epoxy-4-vinylcyclohexane

C

7,8-Epoxy-1-Cyclohexene
5116-65-4

7,8-Epoxy-1-Cyclohexene

D

tetrachloroacetone hydrate
78950-58-0

tetrachloroacetone hydrate

Conditions
ConditionsYield
With disodium hydrogenphosphate; dihydrogen peroxide In chloroform for 24h; Ambient temperature;A 2%
B 60%
C 2.5%
D n/a
With disodium hydrogenphosphate; dihydrogen peroxide In chloroform for 24h; Ambient temperature;A 2%
B 60%
C 1.5%
D n/a
4-ethenylcyclohexene
100-40-3

4-ethenylcyclohexene

A

4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

B

1,2-Epoxy-4-vinylcyclohexane
106-86-5

1,2-Epoxy-4-vinylcyclohexane

C

7,8-Epoxy-1-Cyclohexene
5116-65-4

7,8-Epoxy-1-Cyclohexene

Conditions
ConditionsYield
With dimethylammonium tetrakis(diperoxotungsto)phosphate; dihydrogen peroxide In benzene at 60℃; for 1h;A 3 % Chromat.
B 83 % Chromat.
C 2 % Chromat.
With dihydrogen peroxide; cetylpyridinium bromide; H3PMo10W2O40 In acetonitrile at 60℃; for 3h; Product distribution; Further Variations:; Catalysts; Solvents; Temperatures;
4-ethenylcyclohexene
100-40-3

4-ethenylcyclohexene

A

4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

B

1,2-Epoxy-4-vinylcyclohexane
106-86-5

1,2-Epoxy-4-vinylcyclohexane

Conditions
ConditionsYield
With tert.-butylhydroperoxide; silica gel; molybdenum trioxide In decane at 50℃; for 12h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With air; bis(hexafluoroacetylacetonato)cobalt; isobutyraldehyde In 1,2-dichloro-ethane at 20℃; under 7600 Torr; for 24h; Product distribution; Further Variations:; Reagents; Pressures;A 20 % Chromat.
B 80 % Chromat.
With air; bis(hexafluoroacetylacetonato)cobalt; isobutyraldehyde In 1,2-dichloro-ethane at 20℃; under 7600 Torr; for 24h;A 20 % Chromat.
B 80 % Chromat.
With [Mn(CF3SO3)2(H,MePyTACN)]; dihydrogen peroxide; acetic acid In acetonitrile at 0℃; for 1.5h; chemoselective reaction;
methanol
67-56-1

methanol

4-ethenylcyclohexene
100-40-3

4-ethenylcyclohexene

A

4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

B

1,2-Epoxy-4-vinylcyclohexane
106-86-5

1,2-Epoxy-4-vinylcyclohexane

C

7,8-Epoxy-1-Cyclohexene
5116-65-4

7,8-Epoxy-1-Cyclohexene

D

cyclohex-3-enyl acetaldehyde
24480-99-7

cyclohex-3-enyl acetaldehyde

F

2-Methoxy-5-vinyl-cyclohexanol

2-Methoxy-5-vinyl-cyclohexanol

G

C9H16O2
1243451-21-9

C9H16O2

Conditions
ConditionsYield
With dihydrogen peroxide In water at 64.84℃; for 2h; regioselective reaction;
4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

carbon dioxide
124-38-9

carbon dioxide

cis-5-(2-oxo-1,3-dioxolan-4-yl)hexahydrobenzo[d][1,3]dioxol-2-one

cis-5-(2-oxo-1,3-dioxolan-4-yl)hexahydrobenzo[d][1,3]dioxol-2-one

Conditions
ConditionsYield
With C20H13FeN2O5; tetrabutylammomium bromide at 100℃; under 3750.38 - 7500.75 Torr; for 12h; Sealed tube;99%
4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

carbon dioxide
124-38-9

carbon dioxide

C10H12O6

C10H12O6

Conditions
ConditionsYield
With tetrabutylammomium bromide In neat (no solvent) at 100℃; for 12h; chemoselective reaction;99%
4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

carbon dioxide
124-38-9

carbon dioxide

C10H12O6

C10H12O6

Conditions
ConditionsYield
With calcium iodide In neat (no solvent) at 90℃; under 37503.8 Torr; for 48h; diastereoselective reaction;93%
4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

carbon dioxide
124-38-9

carbon dioxide

4-(7-oxabicyclo[4.1.0]heptan-3-yl)-1,3-dioxolan-2-one

4-(7-oxabicyclo[4.1.0]heptan-3-yl)-1,3-dioxolan-2-one

Conditions
ConditionsYield
With 18-crown-6 ether; calcium iodide In neat (no solvent) at 23℃; under 760.051 Torr; for 24h;92%
4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

n-butyl magnesium bromide
693-03-8

n-butyl magnesium bromide

6-pentyl-7-oxabicyclo<3.2.1>octan-2-ol

6-pentyl-7-oxabicyclo<3.2.1>octan-2-ol

Conditions
ConditionsYield
With triphenylphosphine; copper(I) bromide 1.) THF, Et2O, 0 deg C, 30 min, 2.) THF, Et2O, 0 deg C, 2 h; Yield given; Multistep reaction;
4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

polymer, from photosensitized cationic polymerization; monomer(s): 4-vinylcyclohexene dioxide

polymer, from photosensitized cationic polymerization; monomer(s): 4-vinylcyclohexene dioxide

Conditions
ConditionsYield
With 10-(2-(vinyloxy)ethyl)-10H-phenothiazine; (4-n-decyloxyphenyl) phenyliodonium hexafluoroantimonate at 20℃; Product distribution; Further Variations:; Reagents; UV-irradiation;
4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

4-(1,2-dihydroxyethyl)cyclohexane-1,2-diol
5581-28-2

4-(1,2-dihydroxyethyl)cyclohexane-1,2-diol

Conditions
ConditionsYield
With sulfuric acid In water; acetone
4-vinylcyclohexene dioxide
106-87-6

4-vinylcyclohexene dioxide

2,2,4-trimethyl-decahydro-quinoline
65125-45-3

2,2,4-trimethyl-decahydro-quinoline

1-[2'-hydroxy-2'-(3,4-epoxycyclohexyl)ethyl]-2,2,4-trimethyldecahydroquinoline
65825-48-1

1-[2'-hydroxy-2'-(3,4-epoxycyclohexyl)ethyl]-2,2,4-trimethyldecahydroquinoline

Conditions
ConditionsYield
With Hg In ethylene glycol

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